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Capsaicin is the molecule in chili peppers responsible for the hot or burning sensation you experience upon eating the peppers or handling them. The capsaicin molecule stimulates the nervous system, which is why it produces the burning sensation. There are several medical applications of capsaicin, including as a topical treatment for certain kinds of pain.
Aside form cancer, this is also advisable for osteoarthritis. Capsaicin, also known as Zostrix, is available without a prescription. It is a pain reliever that comes in a cream that you apply directly to your skin. It is a topical analgesic. It has been found to relieve joint pain from osteoarthritis in some people when rubbed into the skin over affected joints. To help, the cream must be applied three or four times a day and the effects may not be seen for several weeks.
The main ingredient in capsaicin is an extract from hot peppers. It appears to have no serious side effects. However some people may be allergic to capsaicin.